Wolfram Uhlig: Catalogue data in Spring Semester 2018

Name Dr. Wolfram Uhlig
Address
Lehre Chemie u. Ang. Biowiss.
ETH Zürich, HCI H 107
Vladimir-Prelog-Weg 1
8093 Zürich
SWITZERLAND
Telephone044 632 28 94
E-mailwuhlig@retired.ethz.ch
DepartmentChemistry and Applied Biosciences
RelationshipLecturer

NumberTitleECTSHoursLecturers
529-0012-02LGeneral Chemistry (Inorganic Chemistry) II4 credits3V + 1UH. Grützmacher, W. Uhlig
Abstract1) General definitions 2) The VSEPR model 3) Qualitative molecular orbital diagrams 4) Closest packing, metal structures 5) The Structures of metalloids
6) Structures of the non-metals 7) Synthesis of the elements 8) Reactivity of the elements 9) Ionic Compounds 10) Ions in Solution 11) Element hydrogen compounds 12) Element halogen compounds 13) Element oxygen compounds 14) Redox chemistry
ObjectiveUnderstanding of the fundamental principles of the structures, properties, and reactivities of the main group elements (groups 1,2 and 13 to 18).
ContentThe course is divided in 14 sections in which the fundamental phenomena of the chemistry of the main group elements are discussed: Part 1: Introduction in the periodical properties of the elements and general definitions –Part 2: The VSEPR model –Part 3: Qualitative molecular orbital diagrams for simple inorganic molecules – Part 4: Closest packing and structures of metals Part 5: The Structures of semimetals (metalloids) of the main group elements –Part 6: Structures of the non-metals– Part 7: Synthesis of the elements. –Part 8: Reactivity of the elements Part 9: Ionic Compounds Part 10: Ions in Solution Part 11: Element hydrogen compounds Part 12: Element halogen compounds Part 13: Element oxygen compounds Part 14: Redox chemistry.
Lecture notesThe transparencies used in the course are accessible via the internet on http://www.gruetzmacher.ethz.ch/education/lectures/lecture-material-allgemeine-chemie---general-chemistry.html
LiteratureJ. Huheey, E. Keiter, R. Keiter, Inorganic Chemistry, Principles and Reactivity, 4th edition, deGruyter, 2003.

C.E.Housecroft, E.C.Constable, Chemistry, 4th edition, Pearson Prentice Hall, 2010.
Prerequisites / NoticeBasis for the understanding of this lecture is the course Allgemeine Chemie 1.
529-2001-AALChemistry I and II Information
Enrolment ONLY for MSc students with a decree declaring this course unit as an additional admission requirement.

All other students (e.g. incoming exchange students, doctoral students) CANNOT enrol for this course unit.
9 credits19RW. Uhlig
AbstractGeneral Chemistry I and II: Chemical bond and molecular structure, chemical thermodynamics, chemical equilibrium, kinetics, acids and bases, electrochemistry
ObjectiveIntroduction to general and inorganic chemistry. Basics of the composition and the change of the material world. Introduction to the thermodynamically controlled physico-chemical processes. Macroscopic phenomena and their explanation through atomic and molecular properties. Using the theories to solve qualitatively and quantitatively chemical and ecologically relevant problems.
Content1. Stoichiometry

2. Atoms and Elements (Quantenmechanical Model of the Atom)

3. Chemical Bonding

4. Thermodynamics

5. Chemical Kinetics

6. Chemical Equilibrium (Acids and Bases, Solubility Equilibria)

7. Electrochemistry
Lecture notesNivaldo J. Tro
Chemistry - A molecular Approach (Pearson), Chapter 1 - 18
LiteratureC. E. Housecroft, E. C. Constable, 'Chemistry'.
529-2002-AALChemistry II
Enrolment ONLY for MSc students with a decree declaring this course unit as an additional admission requirement.

All other students (e.g. incoming exchange students, doctoral students) CANNOT enrol for this course unit.
5 credits11RW. Uhlig, H. Grützmacher
AbstractChemistry II: Redox reactions, chemistry of the elements, introduction to organic chemistry
ObjectiveGeneral base for understanding of inorganic and organic chemistry.
Content1. Redoxreactions

2. Inorganic Chemistry
Rules for nomenclature of inorganic compounds. Systematic description of the groups of elements in the periodical system and the most important compounds of these elements. Formation of compounds as a consequence of the electronoc structure of the elements.

3. Introduction to organic chemistry
Description of the most important classes of compounds and of the functional groups. Principal reactivity of these functional groups.
Stereochemistry.
Rection mechanisms: SN1- and SN2-reactions, electrophilic aromatic subtitutions, eliminations (E1 and E2), addition reactions (C=C and C=O double bonds). Chemistry of carbony and carboxyl groups.
Lecture notesC.E.Housecroft, E.C.Constable, Chemistry, 4rd Edition, Pearson, Harlow (England), 2010 (ISBN 0-131-27567-4), Chap. 18-33
LiteratureTh.L.Brown, H.E.LeMay, B.E.Bursten; Chemie, 10. Auflage, Pearson Studium, München, 2007 (ISBN 3-8273-7191-0)

C.E.Housecroft, E.C.Constable, Chemistry, 3rd Edition, Pearson, Harlow (England), 2010 (ISBN 0-131-27567-4)

D.W.Oxtoby, H.P.Gillis, N.H.Nachtrieb, Principles of Modern Chemistry, Fifth Edition, Thomson, London, 2002 (ISBN 0-03-035373-4)
529-2002-02LChemistry II5 credits2V + 2UW. Uhlig, J. E. E. Buschmann, S. Canonica, P. Funck, H. Grützmacher, E. C. Meister, R. Verel
AbstractChemistry II: Electrochemistry and redox reactions, chemistry of the elements, introduction to organic chemistry
ObjectiveGeneral base for understanding problems of inorganic and organic chemistry.
Content1. Redox reactions and electrochemistry

2. Inorganic Chemistry
Rules for nomenclature of inorganic compounds. Systematic description of the groups of elements in the periodical system and the most important compounds of these elements. Formation of compounds as a consequence of the electronoc structure of the elements.

3. Introduction to organic chemistry
Description of the most important classes of compounds and of the functional groups. Principal reactivity of these functional groups.
Stereochemistry.
Rection mechanisms: SN1- and SN2-reactions, electrophilic aromatic subtitutions, eliminations (E1 and E2), addition reactions (C=C and C=O double bonds). Chemistry of carbony and carboxyl groups.
Lecture notesC.E. Mortimer & U. Müller, CHEMIE, 12. Auflage, Thieme: Stuttgart, 2015 (ISBN 978-3-13-484312-5)
LiteratureTh.L.Brown, H.E.LeMay, B.E.Bursten; Chemie, 10. Auflage, Pearson Studium, München, 2007 (ISBN 3-8273-7191-0)

C.E.Housecroft, E.C.Constable, Chemistry, 3rd Edition, Pearson, Harlow (England), 2006 (ISBN 0-131-27567-4)

D.W.Oxtoby, H.P.Gillis, N.H.Nachtrieb, Principles of Modern Chemistry, Fifth Edition, Thomson, London, 2002 (ISBN 0-03-035373-4)
529-3002-00LChemistry II5 credits2V + 2UW. Uhlig, P. J. Walde, W. R. Caseri
AbstractGeneral Chemistry II: Chemical bonding, Introduction to organic chemistry, Overview on important classes of inorganic compounds
ObjectiveGeneral base for understanding principles of organic chemistry (structure and reaktivity).
Content1. Chemical Bonding
2. Alkanes, alkenes, alkines
3. Arenes
4. Halogenalkanes
5. Aldehydes and ketones
6. Carboxylic acids
7. Amines
8. Natural products
9. Overview on important classes of inorganic compounds
LiteratureC.E. Mortimer & U. Müller, CHEMIE, 12. Auflage, Thieme: Stuttgart, 2015 (ISBN -978-3-13-484312-5)