Search result: Catalogue data in Autumn Semester 2016

Chemistry Bachelor Information
5. Semester
Compulsory Subjects Examination Block II
NumberTitleTypeECTSHoursLecturers
529-0132-00LInorganic Chemistry III: Organometallic Chemistry and Homogeneous CatalysisO4 credits3GA. Togni, A. Mezzetti
AbstractFundamental aspects of the organometallic chemistry ot the transition elements. Mechanistic homogeneous catalysis including oxidative additions, reductive eliminations and insertion reactions. Catalytic hydrogenation, carbonylation, C-C bond-forming and related reactions.
ObjectiveTowards an understanding of the fundamental coordination-chemical and mechanistic aspects of transition-metal chemistry relevant to homogeneous catalysis.
ContentFundamental aspects of the organometallic chemistry ot the transition elements. Mechanistic homogeneous catalysis including oxidative additions, reductive eliminations and insertion reactions. Catalytic hydrogenation, carbonylation, C-C bond-forming and related reactions.
529-0231-00LOrganic Chemistry III: Introduction to Asymmetric SynthesisO4 credits3GE. M. Carreira
AbstractMethods of Asymmetric Synthesis
ObjectiveUnderstanding of the basic principles of diastereoselective synthesis
ContentConformational analysis: acyclic and cyclic systems; Diastereoselective sigmatropic rearrangements; Diastereoselective Carbonyl addition reactions: Cram- and Felkin-Anh models, carbonyl Lewis acid interactions, chelate controlled reactions; chemistry of enolates, selective formation; asymmetic enolate alkylation; aldol reactions, allyl- and crotyl-metal chemistry; cyclisations, Baldwin rules; Diastereoselective olefin functionalization: hydroboration, dihydroxylation, epoxidation.
LiteratureE. M. Carreira and L. Kvaerno Classics in Stereoselective Synthesis, Wiley-VCH 2009

Evans' Problems in Organic Chemistry App
529-0432-00LPhysical Chemistry IV: Magnetic ResonanceO4 credits3GB. H. Meier, M. Ernst, G. Jeschke, R. Riek
AbstractTheoretical foundations of magnetic resonance (NMR,EPR) and selected applications.
ObjectiveIntroduction to magnetic resonance in isotropic and anisotropic phase.
ContentThe course gives an introduction to magnetic resonance spectroscopy (NMR and EPR) in liquid, liquid crystalline and solid phase. It starts from a classical description in the framework of the Bloch equations. The implications of chemical exchange are studied and two-dimensional exchange spectroscopy is introduced. An introduction to Fourier spectroscopy in one and two dimensions is given and simple 'pulse trickery' is described. A quantum-mechanical description of magnetic resonance experiments is introduced and the spin Hamiltonian is derived. The chemical shift term as well as the scalar, dipolar and quadrupolar terms are discussed. The product-operator formalism is introduced and various experiments are described, e.g. polarization transfer. Applications in chemistry, biology, physics and medicine, e.g. determination of 3D molecular structure of dissolved molecules, determination of the structure of paramagnetic compounds and imaging (MRI) are presented.
Lecture noteshanded out in the lecture (in english)
Literaturesee Link
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