Search result: Catalogue data in Spring Semester 2019
Chemistry Bachelor  | ||||||
 Bachelor Studies (Programme Regulations 2018) | ||||||
| 2. Semester | ||||||
| Compulsory Subjects First Year Examinations | ||||||
| Number | Title | Type | ECTS | Hours | Lecturers | |
|---|---|---|---|---|---|---|
| 529-0012-02L | General Chemistry (Inorganic Chemistry) II | O | 4 credits | 3V + 1U | H. Grützmacher, W. Uhlig | |
| Abstract | 1) General definitions 2) The VSEPR model 3) Qualitative molecular orbital diagrams 4) Closest packing, metal structures 5) The Structures of metalloids 6) Structures of the non-metals 7) Synthesis of the elements 8) Reactivity of the elements 9) Ionic Compounds 10) Ions in Solution 11) Element hydrogen compounds 12) Element halogen compounds 13) Element oxygen compounds 14) Redox chemistry | |||||
| Learning objective | Understanding of the fundamental principles of the structures, properties, and reactivities of the main group elements (groups 1,2 and 13 to 18). | |||||
| Content | The course is divided in 14 sections in which the fundamental phenomena of the chemistry of the main group elements are discussed: Part 1: Introduction in the periodical properties of the elements and general definitions –Part 2: The VSEPR model –Part 3: Qualitative molecular orbital diagrams for simple inorganic molecules – Part 4: Closest packing and structures of metals Part 5: The Structures of semimetals (metalloids) of the main group elements –Part 6: Structures of the non-metals– Part 7: Synthesis of the elements. –Part 8: Reactivity of the elements Part 9: Ionic Compounds Part 10: Ions in Solution Part 11: Element hydrogen compounds Part 12: Element halogen compounds Part 13: Element oxygen compounds Part 14: Redox chemistry. | |||||
| Lecture notes | The transparencies used in the course are accessible via the internet on Link | |||||
| Literature | J. Huheey, E. Keiter, R. Keiter, Inorganic Chemistry, Principles and Reactivity, 4th edition, deGruyter, 2003. C.E.Housecroft, E.C.Constable, Chemistry, 4th edition, Pearson Prentice Hall, 2010. | |||||
| Prerequisites / Notice | Basis for the understanding of this lecture is the course Allgemeine Chemie 1. | |||||
| 529-0012-03L | General Chemistry (Organic Chemistry) II | O | 4 credits | 3V + 1U | P. Chen | |
| Abstract | Classification of organic reactions, reactive intermediates: radicals, carbocations, carbanions, electrophilic aromatic substitution, electrophilic addition to double bonds, HSAB concept, nucleophilic substitution at sp3 hybridized carbon centres (SN1/SN2 reactions), nucleophilic aromatic substitutions, eliminations, oxidations, reductions. | |||||
| Learning objective | Understanding of fundamental reactivity principles and the relationship between structure and reactivity. Knowledge of the most important raection types and of selected classes of compounds. | |||||
| Content | Classification of organic reactions, reactive intermediates: radicals, carbocations, carbanions, electrophilic aromatic substitution, electrophilic addition to double bonds, HSAB concept, nucleophilic substitution at sp3 hybridized carbon centres (SN1/SN2 reactions), nucleophilic aromatic substitutions, eliminations, oxidations, reductions. | |||||
| Lecture notes | pdf file available at the beginning of the course | |||||
| Literature | [1] P. Sykes, "Reaktionsmechanismen der Organischen Chemie", VCH Verlagsgesellschaft, Weinheim 1988. [2] Carey/Sundberg, Advanced Organic Chemistry, Part A and B, 3rd ed., Plenum Press, New York, 1990/1991. Deutsch: Organische Chemie. [3] Vollhardt/Schore, Organic Chemistry, 2th ed., Freeman, New York, 1994 Deutsche Fassung: Organische Chemie 1995, Verlag Chemie, Wein¬heim, 1324 S. Dazu: N. Schore, Arbeitsbuch zu Vollhardt, Organische Chemie, 2. Aufl. Verlag Chemie, Weinheim, 1995, ca 400 S. [4] J. March, Advanced Organic Chemistry; Reactions, Mechanisms, and Structure, 5th ed., Wiley, New York, 1992. [5] Streitwieser/Heathcock, Organische Chemie, 2. Auflage, Verlag Chemie, Weinheim, 1994. [6] Streitwieser/Heathcock/Kosower, Introduction to Organic Chemistry, 4th ed., MacMillan Publishing Company, New York, 1992. [7] P. Y. Bruice, Organische Chemie, 5. Auflage, Pearson Verlag, 2007. | |||||
| 529-0012-01L | Physical Chemistry I: Thermodynamics | O | 4 credits | 3V + 1U | F. Merkt | |
| Abstract | Foundations of chemical thermodynamics. The first, second and third law of thermodynamics: Thermodynamic temperature scale, internal energy, enthalpy, entropy, the chemical potential. Solutions and mixtures, phase diagrams. Reaction thermodynamics: reaction parameters and equilibrium conditions, equilibrium constants. Thermodynamics of processes at surfaces and interfaces. | |||||
| Learning objective | Introduction to chemical thermodynamics | |||||
| Content | The first, second and third law of thermodynamics: empirical temperature and thermodynamic temperature scale, internal energy, entropy, thermal equilibrium. Models and standard states: ideal gases, ideal solutions and mixtures, real gases, real solutions and mixtures, activity, tables of standard thermodynamic quantities. Reaction thermodynamics: the chemical potential, reaction parameters and equilibrium conditions, equilibrium constants and their pressure and temperature dependence. Phase equilibria. Thermodynamics at surfaces and interfaces: Adsorption equilibria. Capillary forces. Adsorption isothermes. | |||||
| Lecture notes | See homepage of the lecture. | |||||
| Literature | See homepage of the lecture. | |||||
| Prerequisites / Notice | Requirements: Allgemeine Chemie I, Grundlagen der Mathematik | |||||
| 402-0044-00L | Physik II | O | 4 credits | 3V + 1U | J. Home | |
| Abstract | Introduction to the concepts and tools in physics with the help of demonstration experiments: electromagnetism, optics, introduction to modern physics. | |||||
| Learning objective | The concepts and tools in physics, as well as the methods of an experimental science are taught. The student should learn to identify, communicate and solve physical problems in his/her own field of science. | |||||
| Content | Electromagnetism (electric current, magnetic fields, electromagnetic induction, magnetic materials, Maxwell's equations) Optics (light, geometrical optics, interference and diffraction) Short introduction to quantum physics | |||||
| Lecture notes | The lecture follows the book "Physik" by Paul A. Tipler. | |||||
| Literature | Paul A. Tipler and Gene Mosca Physik Springer Spektrum Verlag | |||||
| 401-0272-00L | Mathematical Foundations I: Analysis B | O | 3 credits | 2V + 1U | L. Kobel-Keller | |
| Abstract | Basics about multidimensional analysis. Ordinary differential equations as mathematical models to describe processes (continuation from Analysis A). Numerical, analytical and geometrical aspects of differential equations. | |||||
| Learning objective | Introduction to calculus in several dimensions. Building simple models and analysing them mathematically. Knowledge of the basic concepts. | |||||
| Content | Basics about multidimensional analysis. Differential equations as mathematical models to describe processes. Numerical, analytical and geometrical aspects of differential equations. | |||||
| Literature | - G. B. Thomas, M. D. Weir, J. Hass: Analysis 2, Lehr- und Übungsbuch, Pearson-Verlag - D. W. Jordan, P. Smith: Mathematische Methoden für die Praxis, Spektrum Akademischer Verlag - M. Akveld/R. Sperb: Analysis I, Analysis II (vdf) - L. Papula: Mathematik für Ingenieure und Naturwissenschaftler Bde 1,2,3. (Vieweg) Further reading suggestions will be indicated during the lecture. | |||||
| 401-0622-00L | Mathematical Foundations II: Linear Algebra and Statistics | O | 3 credits | 2V + 1U | M. Dettling | |
| Abstract | Systems of linear equations; matrix algebra, determinants; vector spaces, norms and scalar products; linear maps, basis transformations; eigenvalues and eigenvectors. Random variables and probability, discrete and continuous distribution models; expectation, variance, central limit theorem, parameter estimation; statistical hypothesis tests; confidence intervals; regression analysis. | |||||
| Learning objective | A sound knowledge of mathematics is an essential prerequisite for a quantitative and computer-based approach to natural sciences. In an intensive two-semester course the most important basic concepts of mathematics, namely univariate and multivariate calculus, linear algebra and statistics are taught. | |||||
| Content | Systems of linear equations; matrix algebra, determinants; vector spaces, norms and scalar products; linear maps, basis transformations; eigenvalues and eigenvectors. - Least squares fitting and regression models; random variables, statistical properties of least-squares estimators; tests, confidence and prediction intervals in regression models; residual analysis. | |||||
| Lecture notes | For the part on Linear Algebra, there is a short script (in German) which summarizes the main concepts and results without examples. For a self-contained presentation, the book by Nipp and Stoffer should be used. For the part on Statistics there is a detailed script (in German) available which should be self-contained. The book by Stahel can be used for additional information. | |||||
| Literature | Linear Algebra: K. Nipp/D. Stoffer: "Lineare Algebra", vdf, 5th edition, 2002. Statistics: W. Stahel, "Statistische Datenanalyse", Vieweg, 5rd edition, 2008. | |||||
| Laboratory Courses | ||||||
| Number | Title | Type | ECTS | Hours | Lecturers | |
| 529-0230-00L | Inorganic and Organic Chemistry I  Enrolment only possible up to the beginning of the semester. | O | 8 credits | 12P | J. W. Bode, M. Jackl, V. R. Pattabiraman | |
| Abstract | Laboratory Course in Inorganic and Organic Chemistry I | |||||
| Learning objective | Introduction into basic techniques used in the organic laboratory. Understanding organic reactions through experiments. | |||||
| Content | Part I: Basic operations such as the isolation, purification and characterization of organic compounds: distillation, extraction, chromatography, crystallization, IR (UV/1H-NMR)-spectroscopy for the identification of the constituion of organic compounds. Part II: Organic reactions: preparative chemistry. From simple, one-step to multistep syntheses. Both classic and modern reactions will be performed. Part III: Preparation of a chiral, enantiomerically pure ligand for asymmetric catalysis (together with AOCP II) | |||||
| Literature | - R. K. Müller, R. Keese: "Grundoperationen der präparativen organischen Chemie"; J. Leonard, B. Lygo, G. Procter: "Praxis der Organischen Chemie" (Übersetzung herausgegeben von G. Dyker), VCH, Weinheim, 1996, ISBN 3-527-29411-2. | |||||
| Prerequisites / Notice | Prerequisites: - Praktikum Allgemeine Chemie (1. Semester, 529-0011-04/05) - Vorlesung Organische Chemie I (1. Semester, 529-0011-03) | |||||
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